Product ID:WHITE 17875DU (08116-02)
MSDS Date:12/18/1985
FSC:8010
NIIN:00-290-6983
MSDS Number: BHGWD

SPRAYON PRODUCTS

3818 EAST CORONADO STREET
ANAHEIM, CA 42807
US

Emergency Phone: 714-630-1400

Info Phone: 714-631-1400

Cage: 5N004

SPRAYON PRODUCTS DIV OF THE SHERWIN-WILLIAMS CO

ANAHEIM, CA 92806 US

Telephone: 714-632-1242

Cage: 5N004

METHYLENE CHLORIDE (SARA III)

CAS: 75-09-2

RTECS: PA8050000

Fraction By Weight: 25%

OSHA PEL 500 PPM/C,1000; Z2

ACGIH TLV: 50 PPM, A2; 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ETHY BETA ETHOXYPROPIONATE (3-ETHOXYETHYL ESTER PROPIONIC

CAS: 763-69-9

RTECS: UF3325000

Fraction By Weight: <5%

OSHA PEL N/K

ACGIH TLV: N/K

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: <5%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 10 - 30%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III)

CAS: 78-93-3

RTECS: EL6475000

Fraction By Weight: 10 - 20%

OSHA PEL 200 PPM/300 STEL

ACGIH TLV: 200 PPM/300STEL 9192

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

A HYDROCARBON BLENDS PSIG.LEL 1.8.

Fraction By Weight: 30%

OSHA PEL N/K

ACGIH TLV: N/K

NAPHTA (PETROLEUM SPIRITS OR BENZIN)

CAS: 8030-30-6

RTECS: DE3030000

Fraction By Weight: 10%

OSHA PEL 100 PPM

LD50 LC50 Mixture:N/K
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:REPORTS HAVE ASSOCIATED PROLONGED AND
REPEATED OVEREXPOSURE TO SOLVENT WITH PERMANENT BRAIN AND NERVOUS
SYSTEM DAMAGE.
Explanation of Carcinogenicity:METHYLENE CHLORIDE:INADEQ EVID FOR
CARCIN IN HUM,SUFF EVID IN ANIM (IARC 1987).ACGIH A2=SUSP HUM
CARCIN (1988 INT CHG).
Effects of Overexposure:EYES:N/K .SKIN:IRRITATION.INGESTION:HARMFUL OR
FATAL IF SWALLOWED.INHALATION:IN CONFINED AREAS,VAPORS IN HIGH
CONCENTRATION ARE ANESTHETIC.IRRITANT TO UPPER RESP
TRACT.OVEREXPOSURE MAY RESU LT IN LIGHT-HEADEDNESS,STAGGERING
GAIT,GIDDINESS AND POSSIBLE NAUSEA.
Medical Cond Aggravated by Exposure:N/K

First Aid:EYES:FLUSH WITH WATER FOR AT LEAST 15 MINUTES.SKIN:WASH WITH
SOAP AND WATER.INGESTIONS:CALL PHYSICIAN IMMEDIATELY.DO NOT INDUCE
VOMITING.INHALATION:REMOVE PATIENT TO FRESH AIR.

Flash Point Method:TOC
Flash Point:SEE SUPP DATA
Lower Limits:N/K
Upper Limits:N/K
Extinguishing Media:CARBON DIOXIDE,DRY CHEMICAL OR FOAM.
Fire Fighting Procedures:WEAR PRESSURE DEMAND SCBA AND FULL PROTECTIVE
EQUIPMENT .WATER MAY BE INEFFECTIVE AS EXTINGUISHING MEDIA BUT MAY
BE USED TO COOL FIRE EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard:DO NOT SPRAY NEAR OPEN FLAME.KEEP AT ROOM
TEMP AS EXPOS TO DIRECT SUNLIGHT OR OTHER HEAT MAY CAUSE
BURSTING.HAZ DECOMP PROD ARE CO,CO*2,HCL,ALSO PHOSGENE

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION,VENTILATE.AVOID
BREATHING VAPORS.REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:N/K

Handling and Storage Precautions:DO NOT STORE ABOVE 120F.49C.KEEP AT
ROOM TEMP AS EXPOS TO DIRECT SUNLIGHT/HEAT MAY CAUSE BURSTING.DO
NOT PUNCTURE,INCINERATE,OR SPRAY NEAR FIRE/FLAME.
Other Precautions:NO SMOKING IN AREA OF USE.DO NOT USE IN GENERAL
VICINITY OF ARC WELDING.OPEN FLAMES OR HOT SURFACES.HEAT AND/OR UV
RADIATION MAY CAUSE FORMATION OF HCL &/OR PHOSGENE .KEEP AWAY FROM
CHLIDREN.AVO ID BREATHING OF VAPOR OR SPRAY MIST.

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:LOCAL AND GENERAL VENTILATION NECESSARY TO KEEP AIR
CONCENTRATION BELOW TVL
Protective Gloves:RECOMMENDED FOR PRLNG/RPTD CONTACT.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:N/K .
Work Hygienic Practices:N/K
Supplemental Safety and Health
BP:

HCC:V3
Boiling Pt:B.P. Text:SEE SUPP
Melt/Freeze Pt:M.P/F.P Text:N/K
Decomp Temp:Decomp Text:N/K
Vapor Pres:N/K
Vapor Density:>AIR
Evaporation Rate & Reference:FASTER THAN ETHER.
Solubility in Water:N/K
Appearance and Odor:N/K
Percent Volatiles by Volume:87

Stability Indicator/Materials to Avoid:YES
N/K
Stability Condition to Avoid:TEMPERATURES ABOVE 120F,49C.
Hazardous Decomposition Products:BY OPEN FLAME:CARBON MONOXIDE,CARBON
DIOXIDE,HHDROGEN CHLORIDE,ALSO PHOSGENE .
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH
FEDERAL,STATE AND LOCAL REGULATIONS .DO NOT INCINERATE.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.